Stabilization and Large Nonlinearity of Gold Nanoparticles Functionalized with a π‐Conjugated Polymer

Gold nanoparticles protected by a novel π‐conjugated polymer [poly(p‐phenylene ethynylene) containing pendent disulfide and bipyridine groups] are synthesized and characterized. The polymer can stabilize the gold nanoparticles effectively. The nonlinear optical properties of the gold nanoparticle colloid solutions in toluene are investigated by using the Z‐scan technique at a wavelength of 532 nm and pulse width of 4 ns. The gold‐nanoparticle colloid solutions show an exceptional nonlinear absorption effect, which simultaneously contains the saturated absorption resulting from third‐order nonlinearity and a large reverse‐saturated absorption resulting from fifth‐order nonlinearity. In addition, asymmetric self‐focusing refractive effects are investigated in the colloid solutions.     

Some classes of analytic and multivalent functions involving a linear operator

By using a linear operator, which is defined here by means of the Hadamard product (or convolution), the authors introduce some new classes of analytic and multivalent functions in the open unit disk and investigate their inclusion relationships and convolution properties. Integral transforms of functions in these classes are also discussed.     

双调和方程特征值问题

该文讨论Navier边值条件下的双调和特征值问题 Δ²u=λa(x)u+f(x, u), x∈ Ω, u=Δu=0, x∈ Ω, 解的存在性, 其中Ω R^N(N ≥ 5)是有界光滑区域, Δ²为双调和算子, 权函数a(x)> 0 a. e. 于Ω, 且 a(x)∈L^r(Ω) (r ≥ N/4). 应用变分方法, 得出了在f(x, u)=0的情况下方程的第二特征值, 并研究了它的结构. 同时在f(x, u) 满足一定的条件下, 得出了共振与非共振情形下方程非零解的存在性 .     

关于广义分次局部上同调的tame性的一个结果

设R=＋n∈N0Rn（R=R0[R1]）是分次Noether交换环,（R0,m0）是一个局部环,R＋=＋n∈NRn;设N是一个有限生成Z-分次R-模,这里N、N0、Z分别表示全体正整数、全体非负整数和全体格致所构成的集合．令h=sup{i∈Z｜HR＋^i（N）不是Artin模}．Dibaei和Nazari证明了HR＋^h（N）是tame模．我们将该结果推广到了广义分次局部上同调模的情形．     

酸洗处理对NaEuTiO4的结构、形貌以及电化学性能影响

采用溶胶-凝胶法合成了具有层状钙钛矿结构的NaEuTiO_4(NETO),并利用X射线衍射(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线光电子能谱(XPS)、循环伏安(CV)和充放电循环测试等方法对用稀硝酸溶液酸洗处理后的NETO在结构、形貌和电化学性能方面的变化做了表征。研究结果表明,对于NETO而言,除了文献报道的Na+→Li+离子交换路径外,还存在着Na~+→H~+→Li~+的离子交换路径,即NETO中的Na~+可以跟稀酸中的H~+发生离子交换。交换后得到的化合物HEuTiO_4可以在电池中通过电化学反应的方式转化为LiEuTiO_4。通过这样的路径得到的LETO具有相同优异的电化学性能,其中酸洗12 h的NETO具有最佳的电化学性能,经过300次循环后,其可逆容量约为213.2 mAh·g~(-1),而且表现出良好的倍率性能。     

六角多铁性HoMnO3的电子和能带结构

基于密度泛函理论(DFT)结合投影缀加平面波(PAW)方法, 运用广义梯度近似(GGA), 在考虑电子基态自旋阻挫非共线的磁性结构基础上, 研究了具有六角钙钛矿结构HoMnO₃材料的磁性、电子和能带结构, 并解释了相关实验结果. 结果表明: 当考虑Mn³⁺离子的电子自旋在平面内呈阻挫的三角非共线反铁磁(NAFM)排列时, 六角HoMnO₃的总能降低、能隙变大、磁矩增大、各原子的位置更接近于实验值, 电子态密度(DOS)分布具有与X光吸收谱测量更为一致的结果. 对非共线磁性结构计算得到的电子态密度和能带结构的分析发现, 实验中观察到的1.7和2.3 eV两个光学吸收峰都源于Mn³⁺离子3d与平面内O(3, 4) 2p形成的杂化态与Mn [3d_3z²-r²]之间的电子跃迁, 而Ho 5d空轨道与平面上的O(3, 4) 2p轨道之间在z方向的强烈杂化驱动HoMnO₃产生垂直于平面方向的铁电极化.     

One-dimensional HKUST-1 nanobelts from Cu nanowires

The controllable synthesis of one-dimensional(1D) structural morphology of metal-organic frameworks(MOFs) is significant for its application in catalysis,sense and gas separation.In this communication,we report a simple and moderate synthetic strategy to obtain uniform HKUST-1 nanobelts(NBs) by using copper nanowires(Cu NWs) as a metal source as well as a template.The control experiments showed that synergy between metal dissolution rate and crystal formation plays a key role in the formation of nanobelts.Our study represents an attractive synthetic strategy of 1 D MOFs-based material for applications.     

Independently tunable transmission-type magneto-optical isolators based on multilayers containing magnetic materials

We investigate the magneto-optical (MO) properties of multilayers containing several magnetic defects. Our numerical simulations show that each MO defect mode can be tuned independently by adjusting the structural parameters of magnetic materials. In addition, giant Faraday rotation can be obtained. Our results indicate that the structure may have potential applications for independently tunable multichannel MO isolators.     

基于传输矩阵法讨论光疏介质表面的全反射

探究了光在光密介质与超薄光疏介质界面处的全反射,通过在光密介质中嵌入一光疏介质薄层,利用传输矩阵法,定量地分析了入射角度以及光疏介质的厚度对反射率的影响.数值模拟结果表明,当光疏介质的厚度小于约一个波长时,即使入射角大于全反射的临界角,反射率也不一定会达到1,也就是说,光学隧道效应将会出现.     

溅射制备Ta2O5薄膜的表面形貌与光学特性

在室温条件下利用溅射Ta₂O₅靶材的方法制备了Ta₂O₅薄膜,并采用将薄膜两侧的反射率光谱进行比较的简便方法分析评估薄膜的光吸收,发现溅射制备薄膜的额外光吸收源是溅射引起的缺氧形成的,选择适当的溅射功率和含氧比例的工作气体能有效地消除这些缺陷、不用任何加温处理就可制备得到表面平坦和高致密度的高品质Ta₂O₅薄膜. 关键词： 2O₅薄膜')" href="#">Ta₂O₅薄膜 光吸收 表面形貌 磁控溅射